Theory of nuclear motion in RABBITT spectra

Autor:	Serguei Patchkovskii, Jakub Benda, Dominik Ertel, David Busto
Rok vydání:	2023
Předmět:	Chemical Physics (physics.chem-ph) Physics - Chemical Physics FOS: Physical sciences
Zdroj:	Physical Review A. 107
ISSN:	2469-9934 2469-9926
DOI:	10.1103/physreva.107.043105
Popis:	Reconstruction of attosecond beating by interference of two-photon transitions (RABBITT) is a powerful photoelectron spectroscopy, offering direct access to internal dynamics of the target. It is being increasingly applied to molecular systems, but a general, computationally tractable theory of RABBITT spectra in molecules has so far been lacking. We show that under quite general assumptions, RABBITT spectra in molecules can be expressed as a convolution of the vibronic cross-correlation functions and two-electron photoionization matrix elements. We specialize the general expressions to the commonly-encountered special cases. We expect our theory to enable accurate modeling and interpretation of molecular RABBITT spectra in most medium-sized molecules. 11 pages, no figures
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ef4d6b97bc2bf02341cb0e61b94bfa02 https://doi.org/10.1103/physreva.107.043105 Zobrazit plný text záznamu