An All-Ceramic, Anisotropic, and Flexible Aerogel Insulation Material

Autor: Yulong Huang, Shenqiang Ren, Donghui Zhao, Zheng Li, Andre Omer Desjarlais, Yong Hu, Zefan Shao, Jason N. Armstrong, Changning Li, Karen L. Hanson, Hamilton Jason M, Lu An, Donald Petit, Mauricio Souza, Yuzi Liu, Jieyu Wang
Rok vydání: 2020
Předmět:
Zdroj: Nano Letters. 20:3828-3835
ISSN: 1530-6992
1530-6984
DOI: 10.1021/acs.nanolett.0c00917
Popis: To exploit the high-temperature superinsulation potential of anisotropic thermal management materials, the incorporation of ceramic aerogel into the aligned structural networks is indispensable. However, the long-standing obstacle to exploring ultralight superinsulation ceramic aerogels is the inaccessibility of its mechanical elasticity, stability, and anisotropic thermal insulation. In this study, we report a recoverable, flexible ceramic fiber-aerogel composite with anisotropic lamellar structure, where the interfacial cross-linking between ceramic fiber and aerogel is important in its superinsulation performance. The resulting ultralight aerogel composite exhibits a density of 0.05 g/cm3, large strain recovery (over 50%), and low thermal conductivity (0.0224 W m-1 K-1), while its hydrophobicity is achieved by in situ trichlorosilane coating with the water contact angle of 135°. The hygroscopic tests of such aerogel composites demonstrate a reversible thermal insulation. The mechanical elasticity and stability of the anisotropic composites, with its soundproof performance, shed light on the low-cost superelastic aerogel manufacturing with scalability for energy saving building applications.
Databáze: OpenAIRE