N,N′-Bis[2,6-bis(1-methylethyl)phenyl]pyridine-4-carboximidamide toluene hemisolvate
| Autor: | Garry S. Hanan, Mihaela Cibian, Sarah Girard, Lola Cottin |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
crystal structure
Imine Substituent Crystal structure 010402 general chemistry 01 natural sciences Medicinal chemistry Research Communications lcsh:Chemistry Amidine chemistry.chemical_compound Pyridine bulky arylamidine General Materials Science 010405 organic chemistry Chemistry Hydrogen bond General Chemistry hydrogen bonding Condensed Matter Physics Toluene 3. Good health 0104 chemical sciences lcsh:QD1-999 Amine gas treating bulky arylamidine |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications Acta Crystallographica Section E: Crystallographic Communications, Vol 77, Iss 2, Pp 117-120 (2021) |
| ISSN: | 2056-9890 |
| Popis: | A new member of the bulky N,N′-bis(2,6-diisopropylphenyl)arylamidine family is reported herein: the N,N′-bis(2,6-diisopropylphenyl)-4-pyridylamidine is a symmetrically N,N′-disubstituted arylamidine containing a 4-pyridyl substituent on the carbon atom of the N–C–N linkage and bulky 2,6-diisopropylphenyl groups on the nitrogen atoms. The title compound, C30H39N3·0.5C7H8, is a symmetrically N,N′-disubstituted arylamidine containing a 4-pyridyl substituent on the carbon atom of the N–C–N linkage and bulky 2,6-diisopropylphenyl groups on the nitrogen atoms. It crystallizes in the Z-anti configuration and its amidine C—N bonds present amine [1.368 (1) Å] and imine [1.286 (1) Å] features. Intramolecular hydrogen bonds are present in the structure together with intermolecular N—H⋯N and C—H⋯N interactions linking the molecules in chains along the a- and c-axis directions. |
| Databáze: | OpenAIRE |
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