Structural characterization of molybdenum–dinitrogen complex as key species toward ammonia formation by dispersive XAFS spectroscopy
| Autor: | Kazunari Yoshizawa, Akira Yamamoto, Hisao Yoshida, Kazuo Kato, Kazuya Arashiba, Shimpei Naniwa, Hiromasa Tanaka, Yoshiaki Nishibayashi |
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| Rok vydání: | 2020 |
| Předmět: |
Materials science
Atmospheric pressure 010405 organic chemistry General Physics and Astronomy chemistry.chemical_element Nitride 010402 general chemistry 01 natural sciences 0104 chemical sciences X-ray absorption fine structure chemistry.chemical_compound chemistry Molybdenum Physical chemistry Physical and Theoretical Chemistry Triiodide Spectroscopy Pincer ligand Stoichiometry |
| Zdroj: | Physical Chemistry Chemical Physics. 22:12368-12372 |
| ISSN: | 1463-9084 1463-9076 |
| DOI: | 10.1039/c9cp06761b |
| Popis: | The structural characterization of a hardly-isolatable molybdenum-dinitrogen complex bearing a PNP-type pincer ligand, which is assumed to be a key reactive complex in the stoichiometric transformation of a molybdenum triiodide complex [MoI3(PNP)] into the corresponding molybdenum nitride complex under an atmospheric pressure of dinitrogen, was carried out by using dispersive XAFS. |
| Databáze: | OpenAIRE |
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