1-(5-Nitro-2-oxoindolin-3-ylidene)thiosemicarbazide
| Autor: | Jörg Daniels, Leandro Bresolin, Adriano Bof de Oliveira, Katlen Crhistian Tribuzy Bandeira, Johannes Beck |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: |
T = 293 K
Mean (C–C) = 0.003 A˚ Crystal structure 5-(4-nitrophenyl)-134-oxadiazol-2-yl Organic Papers Crystal Molecule General Materials Science Single-crystal X-ray study Crystallography Chemistry Hydrogen bond Intermolecular force Thiourea Cristal único wR factor = 0.108 General Chemistry Condensed Matter Physics R factor = 0.041 QD901-999 Intramolecular force Nitro Amine gas treating Data-to-parameter ratio = 12.9 Raios X |
| Zdroj: | Repositório Institucional da FURG (RI FURG) Universidade Federal do Rio Grande (FURG) instacron:FURG Acta Crystallographica Section E, Vol 67, Iss 11, Pp o2858-o2858 (2011) Repositório Institucional da UFS Universidade Federal de Sergipe (UFS) instacron:UFS Acta Crystallographica Section E: Structure Reports |
| Popis: | In the title molecule, C9H7N5O3S, there is an intramolecular N—H...O. The molecule is essentially planar, with the maximum deviation from the mean plane of the 18 non-H atoms being 0.135 (2) Å for the amine N atom. In the crystal, the molecules are connected via intermolecular N—H...O and N—H...S hydrogen bonds, forming two-dimensional networks lying parallel to (10overline4). They are separated by an interplanar distance of 3.3214 (9) Å, leading to π–π interactions which stabilize the crystal structure. |
| Databáze: | OpenAIRE |
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