Poly(thioether)s from Closed-System One-Pot Reaction of Carbonyl Sulfide and Epoxides by Organic Bases
| Autor: | Xin Hong, Xing-Hong Zhang, Tian-Cheng Zhu, Xiao-Han Cao, Cheng-Jian Zhang |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Organic base Closed system General Chemistry Polymer 010402 general chemistry 01 natural sciences Biochemistry Combinatorial chemistry Catalysis 0104 chemical sciences chemistry.chemical_compound Colloid and Surface Chemistry chemistry Thioether One pot reaction Carbonyl sulfide |
| Zdroj: | Journal of the American Chemical Society. 141(13) |
| ISSN: | 1520-5126 |
| Popis: | The synthesis of poly(thioether), a highly desired sulfur-containing polymer, is still a key challenge. Herein, we report a simple and facile approach to poly(thioether)s by closed-system one-pot reaction of carbonyl sulfide (COS) and epoxides. This route underwent the coupling reaction of COS with epoxides, followed by decarboxylative ring-opening polymerization (ROP) of the generated mixed cyclic thiocarbonates with releasing of CO |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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