Functionalization of Zr-based MOFs with alkyl and perfluoroalkyl groups: the effect on the water sorption behavior
| Autor: | Christian Serre, Patricia Horcajada, Emmanuel Magnier, Thomas Devic, Francis Taulelle, C. Yu, Emily Bloch, Fadila Saïdi, Charlotte Martineau, Philip L. Llewellyn, Sandrine Bourrelly, H. Lavrard |
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| Přispěvatelé: | Institut Lavoisier de Versailles (ILV), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Matériaux divisés, interfaces, réactivité, électrochimie (MADIREL), Aix Marseille Université (AMU)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Centre National de la Recherche Scientifique (CNRS)-Aix Marseille Université (AMU)-Institut de Chimie du CNRS (INC) |
| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: |
CO2 ADSORPTION
chemistry.chemical_element 02 engineering and technology Water sorption 010402 general chemistry 01 natural sciences Inorganic Chemistry METAL-ORGANIC FRAMEWORKS UIO-66 Organic chemistry Alkyl chemistry.chemical_classification STABILITY Chemistry Sorption [CHIM.MATE]Chemical Sciences/Material chemistry 021001 nanoscience & nanotechnology SERIES Nitrogen 0104 chemical sciences CAPTURE Solid-state nuclear magnetic resonance Chemical engineering VAPOR Surface modification 0210 nano-technology Powder diffraction STORAGE |
| Zdroj: | Dalton Transactions Dalton Transactions, 2015, 44 (45), pp.19687-19692. ⟨10.1039/c5dt02908b⟩ Dalton Transactions, Royal Society of Chemistry, 2015, 44 (45), pp.19687-19692. ⟨10.1039/c5dt02908b⟩ ResearcherID |
| ISSN: | 1477-9226 1477-9234 |
| DOI: | 10.1039/c5dt02908b⟩ |
| Popis: | International audience; Stability and sorption of Metal-Organic Frameworks (MOFs) towards water are critical in many applications, and can a priori be modulated through the introduction of suitable organic functional groups on their backbone. We report here the preparation of a series of Zr(IV)-based MOFs functionalized with alkyl and perfluoroalkyl groups and their characterization by X-ray powder diffraction, multi-nuclei (H-1, C-13, F-19) solid state nuclear magnetic resonance analyses, and nitrogen sorption measurements at 77 K. Their water sorption behavior was evaluated at 298 K and related to their physico-chemical features, highlighting both the effect of the confinement and the nature of the functional groups on the hydrophilic/hydrophobic balance. |
| Databáze: | OpenAIRE |
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