Dealkylation of alkyl polycyclic aromatic hydrocarbon over silica monolayer solid acid catalyst
| Autor: | Koshiro Nakamura, Masato Nanjo, Shohei Fujiwara, Kazuki Kanai, Kazuki Takeda, Kawaguchi Yusuke, Keisuke Kinugasa, Naoki Uozumi, Satoshi Suganuma, Naonobu Katada, Taku Matsuoka |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
Process Chemistry and Technology Inorganic chemistry Polycyclic aromatic hydrocarbon Silica monolayer solid acid catalyst 02 engineering and technology Alkylation 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Catalysis 0104 chemical sciences law.invention Vacuum gas oil chemistry law Monolayer Calcination 0210 nano-technology Selectivity Brønsted–Lowry acid–base theory Alkyl polycyclic aromatic hydrocarbons dealkylation Alkyl |
| Zdroj: | Katada, Naonobu. Kawaguchi, Yusuke. Takeda, Kazuki. et al. Dealkylation of alkyl polycyclic aromatic hydrocarbon over silica monolayer solid acid catalyst. Applied Catalysis A: General. 530. 93-101. 2017-01-25. |
| ISSN: | 0926-860X |
| Popis: | Dealkylation of alkylnaphthalene, as a model of alkyl polycyclic aromatic hydrocarbon compounds in heavy oils, proceeded selectively on a silica monolayer solid acid catalyst. The activity was generated by the deposition of silica on alumina with generation of Bronsted acidity. The activity and Bronsted acid amount showed the maximum where the monolayer covered the surface, indicating that the Bronsted acid site generated on the silica monolayer was the active species. The activity and selectivity on the silica monolayer were high compared to other aluminosilicate catalysts, and high activity was observed even after calcination at 973–1173 K. |
| Databáze: | OpenAIRE |
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