Structure of a One-Dimensional Copper(I) Polymer with Iodine Bridges
| Autor: | Amagoia Aguirrechu-Comerón, Rita Hernández-Molina, Javier González-Platas |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Trigonal planar molecular geometry
chemistry.chemical_classification Materials science Solid-state physics Ligand chemistry.chemical_element Halide Infrared spectroscopy Polymer 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences Copper 0104 chemical sciences Inorganic Chemistry Crystallography chemistry Materials Chemistry Physical and Theoretical Chemistry Coordination geometry |
| Zdroj: | Journal of Structural Chemistry. 60:472-476 |
| ISSN: | 1573-8779 0022-4766 |
| DOI: | 10.1134/s0022476619030168 |
| Popis: | A novel one-dimensional polymeric Cu(I) halide complex with iodine bridges between copper atoms and 2-phenylquinoline as an N-donor ligand is prepared. The complex is characterized by elemental analyses, IR spectroscopy, and crystallographic studies.The coordination geometry around copper may be described as distorted trigonal planar. The I—Cu—I, Cu—I—Cu, and N—Cu—I angles are 115.90(2), 116.37(2), and 124.80(8)°, respectively. The Cu—I distances range from 2.563(6) to 2.569(6) Å, and the Cu—N bond is 2.016(2) Å, being in good agreement with that in the related structures. |
| Databáze: | OpenAIRE |
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