Rh(I)-catalyzed addition of alkenylzirconocene chlorides to aldimine derivatives

Autor:	Yuji Hanzawa, Takeo Taguchi, Akito Kakuuchi
Rok vydání:	2003
Předmět:	chemistry.chemical_classification Allylic rearrangement Aldimine Addition reaction Organic Chemistry General Medicine Biochemistry Chloride Medicinal chemistry Catalysis chemistry Drug Discovery medicine Organic chemistry Amine derivatives medicine.drug
Zdroj:	Tetrahedron Letters. 44:923-926
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(02)02767-3
Popis:	[RhCl(COD)] 2 (2 mol%) catalyzed reactions of alkenylzirconocene chloride complexes to N -Ts, -PO(OEt) 2 and COOR aldimine derivatives were efficiently carried out in dioxane at room temperature to give allylic amine derivatives in excellent yields. This is the first example of the catalytic addition reactions of alkenylzirconocene chloride complexes to aldimine derivatives.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d50e5f181c102d45b02b1e242bd243a3 https://doi.org/10.1016/s0040-4039(02)02767-3 Zobrazit plný text záznamu Full Text from ScienceDirect