SANS study to probe nanoparticle dispersion in nanocomposite membranes of aromatic polyamide and functionalized silica nanoparticles
| Autor: | Vinod K. Aswal, Puyam S. Singh, Ghanshyam L. Jadav |
|---|---|
| Rok vydání: | 2010 |
| Předmět: |
Nanocomposite
Materials science Surface Properties Dispersity Nanoparticle Membranes Artificial Silicon Dioxide Small-angle neutron scattering Surfaces Coatings and Films Electronic Optical and Magnetic Materials Biomaterials Silicon alkoxide Neutron Diffraction Nylons chemistry.chemical_compound Colloid and Surface Chemistry Membrane chemistry Chemical engineering Scattering Small Angle Polyamide Polymer chemistry Nanoparticles Particle Size Dispersion (chemistry) |
| Zdroj: | Journal of Colloid and Interface Science. 351:304-314 |
| ISSN: | 0021-9797 |
| DOI: | 10.1016/j.jcis.2010.07.028 |
| Popis: | Silica nanoparticles produced from organically functionalized silicon alkoxide precursors were incorporated into polyamide film to produce a silica–polyamide nanocomposite membrane with enhanced properties. The dispersion of the silica nanoparticles in the nanocomposite membrane was characterized by performing small-angle neutron scattering (SANS) measurements on dilute reactant systems and dilute solution suspensions of the final product. Clear scattering of monodisperse spherical particles of 10–18 A R g were observed from dilute solutions of the initial reactant system. These silica nanoparticles initially reacted with diamine monomers of polyamide and subsequently were transformed into polyamide-coated silica nanoparticles; finally nanoparticle aggregates of 27–45 A R g were formed. The nanoparticle dispersion of the membrane as the nanosized aggregates is in corroboration with ring- or chain-like assemblies of the nanoparticles dispersed in the bulk polyamide phase as observed by transmission electron microscopy. It is demonstrated that dispersions of silica nanoparticles as the nanosized aggregates in the polyamide phase could be achieved in the nanocomposite membrane with a silica content up to about 2 wt.%. Nanocomposite membranes with higher silica loading ∼10 wt.% lead to the formation of large aggregates of sizes over 100 A R g in addition to the nanosized aggregates. |
| Databáze: | OpenAIRE |
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