Carbonylative cycloaddition between two different alkenes enabled by reactive directing groups: expedited construction of bridged polycyclic skeletons

Autor: Hanmin Huang, Yongzheng Ding, Guoqing Yang, Suchen Zou, Bingjian Gao
Rok vydání: 2020
Předmět:
Zdroj: Chemical Communications. 56:12198-12201
ISSN: 1364-548X
1359-7345
DOI: 10.1039/d0cc05362g
Popis: A novel palladium-catalyzed highly selective hydrocarbonylative cycloaddition reaction with two different alkenes in the presence of CO enabled by a reactive directing-group is developed, which offers efficient and convenient access to lactone-containing bridged polycyclic compounds in high yield with high chemo- and stereoselectivities.
Databáze: OpenAIRE