Carbonylative cycloaddition between two different alkenes enabled by reactive directing groups: expedited construction of bridged polycyclic skeletons
Autor: | Hanmin Huang, Yongzheng Ding, Guoqing Yang, Suchen Zou, Bingjian Gao |
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Rok vydání: | 2020 |
Předmět: | |
Zdroj: | Chemical Communications. 56:12198-12201 |
ISSN: | 1364-548X 1359-7345 |
DOI: | 10.1039/d0cc05362g |
Popis: | A novel palladium-catalyzed highly selective hydrocarbonylative cycloaddition reaction with two different alkenes in the presence of CO enabled by a reactive directing-group is developed, which offers efficient and convenient access to lactone-containing bridged polycyclic compounds in high yield with high chemo- and stereoselectivities. |
Databáze: | OpenAIRE |
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