Induction Heating in Nanoparticle Impregnated Zeolite
| Autor: | João M. Silva, Mario Quijorna, Irene Morales, M. Rosário Ribeiro, Jose Maria Alonso, Patricia de la Presa, Marta Muñoz, Marta Multigner, Cátia S. Costa |
|---|---|
| Přispěvatelé: | Ministerio de Ciencia, Innovación y Universidades (España), Comunidad de Madrid, Agencia Estatal de Investigación (España), Fundação para a Ciência e a Tecnologia (Portugal) |
| Rok vydání: | 2020 |
| Předmět: |
magnetic nanoparticles
Induction heating Materials science Nanoparticle 02 engineering and technology 010402 general chemistry Fluid catalytic cracking lcsh:Technology induction heating 01 natural sciences Article Catalysis General Materials Science zeolite lcsh:Microscopy Zeolite lcsh:QC120-168.85 catalytic cracking lcsh:QH201-278.5 lcsh:T 021001 nanoscience & nanotechnology 0104 chemical sciences Magnetic hyperthermia Catalytic cracking Chemical engineering lcsh:TA1-2040 Magnetic nanoparticles lcsh:Descriptive and experimental mechanics lcsh:Electrical engineering. Electronics. Nuclear engineering lcsh:Engineering (General). Civil engineering (General) 0210 nano-technology Mesoporous material lcsh:TK1-9971 |
| Zdroj: | Digital.CSIC. Repositorio Institucional del CSIC instname Materials Volume 13 Issue 18 Repositório Científico de Acesso Aberto de Portugal Repositório Científico de Acesso Aberto de Portugal (RCAAP) instacron:RCAAP Materials, Vol 13, Iss 4013, p 4013 (2020) |
| ISSN: | 1996-1944 |
| DOI: | 10.3390/ma13184013 |
| Popis: | The ultra-stable Y (H-USY) zeolite is used as catalyst for the conversion of plastic feedstocks into high added value products through catalytic cracking technologies. However, the energy requirements associated with these processes are still high. On the other hand, induction heating by magnetic nanoparticles has been exploited for different applications such as cancer treatment by magnetic hyperthermia, improving of water electrolysis and many other heterogeneous catalytic processes. In this work, the heating efficiency of γ-Fe2O3 nanoparticle impregnated zeolites is investigated in order to determine the potential application of this system in catalytic reactions promoted by acid catalyst centers under inductive heating. The γ-Fe2O3 nanoparticle impregnated zeolite has been investigated by X-ray diffraction, electron microscopy, ammonia temperature program desorption (NH3-TPD), H2 absorption, thermogravimetry and dc and ac-magnetometry. It is observed that the diffusion of the magnetic nanoparticles in the pores of the zeolite is possible due to a combined micro and mesoporous structure and, even when fixed in a solid matrix, they are capable of releasing heat as efficiently as in a colloidal suspension. This opens up the possibility of exploring the application at higher temperatures. This research was funded by Ministerio de Ciencia e Innovación grant number RTI2018-095856-B-C21, MAT2015-66334-C3-3-R and RTI2018-096391-B-C31, Comunidad de Madrid Projects grant number P2018/NMT-4321 and CM-S2018/NMT-4411; Ayudas a la Movilidad PDI URJC 2018 and PDI URJC 2019 and Fundação para a Ciência e Tecnologia (Project UID/QUI/00100/2019 and FCT-CATSUS grant: PD/BD/12862/2017). The authors also acknowledge the technical support given by Fernando Giacomone financed by Spanish Ministry of Science and Innovation, PTA2015-10497-I. |
| Databáze: | OpenAIRE |
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