gem-Diborylalkanes: recent advances in their preparation, transformation and application

Autor:	Kishor Padala, Ahmad Masarwa, Rajender Nallagonda
Rok vydání:	2018
Předmět:	Chemical transformation 010405 organic chemistry Chemistry Organic Chemistry Nanotechnology 010402 general chemistry 01 natural sciences Biochemistry Transformation (music) 0104 chemical sciences chemistry.chemical_compound Molecule Organic synthesis Physical and Theoretical Chemistry
Zdroj:	Organic & Biomolecular Chemistry. 16:1050-1064
ISSN:	1477-0539 1477-0520
DOI:	10.1039/c7ob02978k
Popis:	Recently, gem-diborylalkanes have attracted much attention as versatile building blocks and fundamental intermediates in organic synthesis, because they enable multiple C-C bond construction and further transformation at C-B bonds. Importantly, gem-diborylalkanes can be utilised as bisnucleophilic partners in a variety of chemo-selective C-C bond-forming reactions. This review describes recent developments in synthesising gem-diborylalkanes in complex molecules along with their chemical transformation. In the first part of the review the different synthetic approaches used to synthesise gem-diborylalkanes are described. In the second part, an overview of the chemoselective transformation of gem-diborylalkanes into various functionalized materials is discussed along with one-carbon homologation of diborylmethane via a selective uni- and bidirectional method.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cda1ff46c6073fbbdfda09a5304c8e6f https://doi.org/10.1039/c7ob02978k Zobrazit plný text záznamu