Synthesis of 2-arylpropionic acids by electrocarboxylation of benzylchlorides catalysed by PdCl2(PPh3)2
| Autor: | J. Damodar, Srinivasulu Reddy Krishna Mohan, Srinivasulu Reddy Jayarama Reddy |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2001 |
| Předmět: |
chemistry.chemical_classification
inorganic chemicals Reaction mechanism Carboxylic acid chemistry.chemical_element Electrocatalyst Electrochemistry Catalysis lcsh:Chemistry chemistry.chemical_compound chemistry Carboxylation lcsh:Industrial electrochemistry lcsh:QD1-999 Carbon dioxide Organic chemistry Palladium lcsh:TP250-261 |
| Zdroj: | Electrochemistry Communications, Vol 3, Iss 12, Pp 762-766 (2001) |
| ISSN: | 1388-2481 |
| Popis: | Electrochemical carboxylation of benzylchlorides catalysed by Pd(II) complex afforded 2-arylpropionic acids in good yields under atmospheric pressure of carbon dioxide at constant current of 10 mA cm−2. Mechanistic and electrochemical studies revealed the cooperative role of reduced palladium species in the activation of carbon dioxide. Keywords: Methylarylhalide, Carbon dioxide, Carboxylic acid, Palladium complex, Catalysis, Cyclic voltammetry |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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