Synthesis of Diazacalix[8]arene and Triazacalix[12]arene Methyl Ethers via Intramolecular Aryl Amination

Autor:	Ashlee C. Barton, John D. Spence, Kenneth V. Lawson
Rok vydání:	2009
Předmět:	Chemistry Intramolecular force Organic Chemistry Regioselectivity Organic chemistry Physical and Theoretical Chemistry Biochemistry Medicinal chemistry Aryl amination
Zdroj:	Organic Letters. 11:895-898
ISSN:	1523-7052 1523-7060
DOI:	10.1021/ol8028912
Popis:	Azacalixarenes derived from p-tert-butylphenol are generated by an intramolecular aryl amination strategy as the ring-closing step. The reaction produces the first examples of larger p-tert-butylcalixarenes with regioselective substitution of bridging methylenes with nitrogen atoms.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c8f195907871c4b13b76bdc61d745fd6 https://doi.org/10.1021/ol8028912 Zobrazit plný text záznamu