Cellulose and Vanadium Plasmonic Sensor to Measure Ni2+ Ions

Autor: Yap Wing Fen, Nur Alia Sheh Omar, Jaafar Abdullah, Umi Zulaikha Mohd Azmi, Irmawati Ramli, Mohd Adzir Mahdi, Hazwani Suhaila Hashim
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Applied Sciences
Volume 11
Issue 7
Applied Sciences, Vol 11, Iss 2963, p 2963 (2021)
ISSN: 2076-3417
DOI: 10.3390/app11072963
Popis: A novel vanadium–cellulose composite thin film-based on angular interrogation surface plasmon resonance (SPR) sensor for ppb-level detection of Ni(II) ion was developed. Experimental results show that the sensor has a linear response to the Ni(II) ion concentrations in the range of 2–50 ppb with a determination coefficient (R2) of 0.9910. This SPR sensor can attain a maximum sensitivity (0.068° ppb−1), binding affinity constant (1.819 × 106 M−1), detection accuracy (0.3034 degree−1), and signal-to-noise-ratio (0.0276) for Ni(II) ion detection. The optical properties of thin-film targeting Ni(II) ions in different concentrations were obtained by fitting the SPR reflectance curves using the WinSpall program. All in all, the proposed Au/MPA/V–CNCs–CTA thin-film-based surface plasmon resonance sensor exhibits better sensing performance than the previous film-based sensor and demonstrates a wide and promising technology candidate for environmental monitoring applications in the future.
Databáze: OpenAIRE