A facile synthesis of 3-allyl-4-hydrazinocyclopentenes by the palladium/Lewis acid mediated ring opening of bicyclic hydrazines with allyltributyltin and allyltrimethylsilane

Autor:	Mohanlal Smitha, Kokkuvayil Vasu Radhakrishnan, V. S. Sajisha, Saithalavi Anas
Rok vydání:	2006
Předmět:	Bicyclic molecule Chemistry Organic Chemistry chemistry.chemical_element General Medicine Ring (chemistry) Biochemistry Catalysis Solvent chemistry.chemical_compound Drug Discovery Polymer chemistry Ionic liquid Organic chemistry Lewis acids and bases Palladium catalyst Palladium
Zdroj:	Tetrahedron. 62:3997-4002
ISSN:	0040-4020
DOI:	10.1016/j.tet.2006.02.028
Popis:	A facile method for the synthesis of 3-allyl-4-hydrazinocyclopentenes from bicyclic hydrazines by the Pd/Lewis acid catalyzed reaction of allyltributyltin and allyltrimethylsilane is described. The role of ionic liquid [bmim]PF 6 as a solvent as well as a promoter is also demonstrated by carrying out the reactions in ionic liquid without Lewis acid.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c6dd5c3c9cbeda7d33864b1ce0b85fbb https://doi.org/10.1016/j.tet.2006.02.028 Zobrazit plný text záznamu Full Text from ScienceDirect