Poly(acrylamide-co-itaconic acid) and semi-IPNS with poly(ethylene glycol): Preparation and characterization
| Autor: | Danijel Danković, Melina Kalagasidis Krušić, Jovanka M. Filipović, Marija Nikolic |
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| Rok vydání: | 2004 |
| Předmět: |
Polymers and Plastics
Polyacrylamide 02 engineering and technology 010402 general chemistry 01 natural sciences chemistry.chemical_compound PEG ratio Polymer chemistry Materials Chemistry medicine Copolymer Itaconic acid Physical and Theoretical Chemistry Ionomer hydrogels Organic Chemistry semi-interpenetrating polymer networks itaconic acid 021001 nanoscience & nanotechnology Condensed Matter Physics 0104 chemical sciences chemistry Self-healing hydrogels Swelling medicine.symptom 0210 nano-technology polyacrylamide Ethylene glycol |
| Zdroj: | Macromolecular Chemistry and Physics |
| Popis: | Summary: A pH-responsive poly(acrylamide-co-itaconic acid) (PAAm/IA) hydrogel and semi-interpenetrating networks (semi-IPNs) with 5, 10 and 15 wt.-% of poly(ethylene glycol) (PAAm/IA/PEG), were synthesized. Their swelling behavior was studied in the pH range from 1.76 to 7.81, as well as their oscillatory swelling behavior at pH = 7.81 and pH = 1.7. Throughout these studies, the gels maintained their mechanical strengths and shape. The shear storage (G′) and loss (G″) moduli, obtained as a function of frequency, for the gels as formed and at equilibrium swelling were higher for the semi-IPNs than for the copolymer hydrogel. The shear storage moduli of copolymer hydrogel and semi-IPNs as formed were independent of frequency over the whole experimental range, whereas the values for the gels at equilibrium swelling decreased with increasing degree of swelling, i.e., the PAAm/IA hydrogel which exhibited the largest swelling had the lowest G′ value. The G′ and G″ values also depended on the content of PEG. Diffusion exponent vs. pH for PAAm, copolymer hydrogel PAAm/IA and semi-IPN with PEG. |
| Databáze: | OpenAIRE |
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