Experimentally designed potentiometric sensor for green real-time and direct assay of hazardous bromate in bakery products

Autor: Mohammed E. Draz, Ahmed S. Saad, Dina El Sherbiny, Mary E.K. Wahba
Rok vydání: 2022
Předmět:
Zdroj: Food chemistry. 406
ISSN: 1873-7072
Popis: Bakeries add extra potassium bromate to the dough to make homogeneous, elastic, fluffy bread. Bromate causes renal damage and cancer. FAO/WHO stated that bromate residues shouldn't be in baked products. A potentiometric sensor's membrane recipe was optimized for sensitive and selective bromate assay. We planned a custom experimental design of 21 sensors that included numerical and categorical factors (NPPE: PVC, matrix%, membrane thickness, and ionophore type). We defined sensor performance outcomes (Nernstian slope, quantification limit, correlation coefficient, response time and selectivity), and each sensor's outcome was determined. The computer software developed a predictive model for each outcome and the desirability function suggested the optimum sensor recipe. The sensor achieved a slope of -63.54 mV/decade and detection limit of 2 × 10
Databáze: OpenAIRE