How to get the desired reduction voltage in a single framework! Metallacarborane as an optimal probe for sequential voltage tuning

Autor:	Màrius Tarrés, Francesc Teixidor, Adnana Zaulet, Clara Viñas, Víctor Sánchez Arderiu, Fabrizia Fabrizi de Biani
Rok vydání:	2015
Předmět:	Paraquat Chemistry Analytical chemistry Derivative Redox Electrolysis Inorganic Chemistry Reduction (complexity) Organometallic Compounds Redox active Moiety Methyl Viologen Oxidation-Reduction Voltage
Zdroj:	Dalton transactions (Cambridge, England : 2003). 44(26)
ISSN:	1477-9234
Popis:	An appealingly wide set of redox couples ranging from -1.74 to -0.35 V based on a metallabisdicarbollide derivative, [M(C2B9H11-yIy)2](-) (M = Co, Fe), each being distinguished from the former by near 0.15 V and all having the same structure have been demonstrated. The redox active methyl viologen moiety ([MV](2+)) has been used as a benchmark.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c3eb4e0b63d72166af0d28825415ef9f https://pubmed.ncbi.nlm.nih.gov/26054738 Zobrazit plný text záznamu