Catalytic Diastereospecific and Enantioselective (3 + 2) Transannulations of 1,2,3-Thiadiazoles with Strained Norbornene Derivatives

Autor:	Cunzhi Chen, Shuyan Fang, Ziyang Dong, Jiaxi Xu, Zhanhui Yang
Rok vydání:	2022
Předmět:	Thiadiazoles Organic Chemistry Stereoisomerism Physical and Theoretical Chemistry Iridium Norbornanes Biochemistry Catalysis
Zdroj:	Organic Letters. 24:2110-2114
ISSN:	1523-7052 1523-7060
DOI:	10.1021/acs.orglett.2c00330
Popis:	With the adoption of a ring-strain-release strategy, iridium-catalyzed transannulations with norbornene derivatives are achieved in a diastereospecific and enantioselective manner. The first asymmetric transannulations of 1,2,3-thiadiazoles are reported.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c344f5146885cdeb556ca82cfe3dc22c https://doi.org/10.1021/acs.orglett.2c00330 Zobrazit plný text záznamu