Instant one-pot preparation of functional layered double hydroxides (LDHs) via a continuous hydrothermal approach
| Autor: | Cyril Aymonier, Oana Pascu, Ghina Ali, Laurence Hecquet, Bastien Cacciuttolo, Mathieu Pucheault, Vanessa Prevot, Samuel Marre |
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| Přispěvatelé: | Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB), Université de Bordeaux (UB)-Institut Polytechnique de Bordeaux-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut des Sciences Moléculaires (ISM), Université Montesquieu - Bordeaux 4-Université Sciences et Technologies - Bordeaux 1 (UB)-École Nationale Supérieure de Chimie et de Physique de Bordeaux (ENSCPB)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut de Chimie de Clermont-Ferrand (ICCF), SIGMA Clermont (SIGMA Clermont)-Institut de Chimie du CNRS (INC)-Université Clermont Auvergne [2017-2020] (UCA [2017-2020])-Centre National de la Recherche Scientifique (CNRS), ANR-12-CDII-0010,NANOCAUSYS,Catalyseurs Nanostructurés en Systèmes Non Conventionnels(2012), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut Polytechnique de Bordeaux-Université de Bordeaux (UB), Centre National de la Recherche Scientifique (CNRS)-École Nationale Supérieure de Chimie et de Physique de Bordeaux (ENSCPB)-Université Sciences et Technologies - Bordeaux 1-Université Montesquieu - Bordeaux 4-Institut de Chimie du CNRS (INC) |
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
Materials science
Renewable Energy Sustainability and the Environment Oxide Layered double hydroxides Energy Engineering and Power Technology Nanoparticle 02 engineering and technology [CHIM.MATE]Chemical Sciences/Material chemistry engineering.material 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Hydrothermal circulation 0104 chemical sciences Biomaterials chemistry.chemical_compound Crystallinity chemistry Chemical engineering Materials Chemistry engineering Hydrothermal synthesis Surface modification 0210 nano-technology Hybrid material |
| Zdroj: | ChemNanoMat ChemNanoMat, 2017, 3 (9), pp.614-619. ⟨10.1002/cnma.201700125⟩ ChemNanoMat, Wiley, 2017, 3 (9), pp.614-619. ⟨10.1002/cnma.201700125⟩ |
| ISSN: | 2199-692X |
| DOI: | 10.1002/cnma.201700125⟩ |
| Popis: | International audience; Instant one-pot synthesis of functional layered double hydroxides (LDHs) is demonstrated for the first time using a continuous hydrothermal multi-step process. The as-prepared pristine material displays high crystallinity and very small LDH nanoparticle size, lateral dimensions below 100 nm and a thickness below 20 nm, all being achieved in only 5 s. This approach was extended to the preparation of i) pristine LDH with different compositions by varying the cation (Mg, Ni, or Zn) and the anion (CO3, NO3) and ii) functional LDH by varying the functionalization agent, for example long organic molecules (hybrid LDH), enzymes (bio-hybrid LDH) or inorganic metal/oxide nanocrystals (inorganic-LDH). Beyond the design of functional LDH, this paper presents proof of concept for a continuous, one-pot and multistep high temperature/high pressure (HT/HP) process for the assembly of nanoscaled materials. |
| Databáze: | OpenAIRE |
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