Production of 5-Hydroxymethylfurfural from D-Fructose in Low-Transition-Temperature Mixtures Enhanced by Chloride Anions and Low Amounts of Organic Acids
| Autor: | Thibaut Istasse, Aurore Richel, Lauris Bockstal |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Maleic acid 010405 organic chemistry General Chemistry 010402 general chemistry 01 natural sciences Chloride 0104 chemical sciences chemistry.chemical_compound chemistry Reagent Ionic liquid medicine Organic chemistry Selectivity Hydroxymethylfurfural Organic acid medicine.drug Choline chloride |
| Zdroj: | ChemPlusChem. 83(12) |
| ISSN: | 2192-6506 |
| Popis: | The use of safe and sustainable solvents able to solvate reagents and to catalyze their reactions at temperatures below 100 °C is an innovative strategy to develop future lignocellulosic biorefineries. Many low-transition-temperature mixtures (LTTMs) have been investigated for this purpose. Among them, natural deep eutectic solvents (NADESs) have been proposed as cheap and renewable alternatives to ionic liquids for the synthesis of bio-based chemical building blocks. We compare herein the ability of several organic acids/choline chloride/water LTTMs to perform D-fructose dehydration to 5-hydroxymethylfurfural (5-HMF). The addition of chloride salts as well as an increased proportion of choline chloride promotes 5-HMF formation, which seems to indicate a beneficial effect of chloride anions on D-fructose dehydration. Besides improving selectivity by at least 10 %, increasing the choline chloride/acid ratio could enhance the biodegradability of the LTTMs. Unlike other acidic components, maleic and citric acids are especially selective at early D-fructose conversion. Maleic acid was the most selective acidic component among the tested chemicals, achieving an 80 % 5-HMF molar yield in 1 h at 90 °C. |
| Databáze: | OpenAIRE |
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