Crystal structure of 2,3-dimeth-oxy-5,6,7,8,13,13a-hexa-hydro-6a,8-di-aza-indeno-[2,1-b]phenanthrene methanol monosolvate
| Autor: | Abdusalom Sh. Saidov, Rasul Ya. Okmanov, Kambarali K. Turgunov, Shahobiddin Adizov, Bakhodir Tashkhodjaev |
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| Rok vydání: | 2015 |
| Předmět: |
Indole test
crystal structure Stereochemistry Hydrogen bond Dimer isoquinoline alkaloid General Chemistry Crystal structure indole alkaloid Condensed Matter Physics HEXA Ring (chemistry) hydrogen bonding Medicinal chemistry Data Reports lcsh:Chemistry isoquinoline alkaloid chemistry.chemical_compound chemistry lcsh:QD1-999 Moiety General Materials Science Methanol |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 8, Pp o574-o575 (2015) |
| ISSN: | 2056-9890 |
| Popis: | The asymmetric unit of the title solvate, C21H22N2O2·CH3OH, contains one methanol solvent molecule and one molecule of the heterocycle that is built up by the fusion of four six-membered ringsA,C,D,Eand one five-membered ringB. The indole moiety (ringsAandB) is essentially planar, with an r.m.s. deviation of 0.013 Å, whereas ringsCandDadopt a twisted conformation with atrans-ring junction. In the crystal, two heterocyclic molecules are associated with two methanol molecules through mutual N—H...O and O—H...N hydrogen bonds, forming a centrosymmetric dimer. |
| Databáze: | OpenAIRE |
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