Enhancement factors in electrochemical surface oxidation enhanced Raman scattering
| Autor: | Sheila Hernandez, Alvaro Colina, Juan V. Perales-Rondon, Aranzazu Heras |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
EC-SOERS
Work (thermodynamics) Materials science General Chemical Engineering 02 engineering and technology Química analítica 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry Electrochemistry EC-SERS 01 natural sciences 0104 chemical sciences symbols.namesake symbols Molecule Surface oxidation Chemistry Analytic 0210 nano-technology Raman spectroscopy Spectroelectrochemistry Surface enhanced Raman scattering Electrochemical surface oxidation enhanced Raman scattering Raman scattering |
| Zdroj: | Repositorio Institucional de la Universidad de Burgos (RIUBU) instname |
| Popis: | Electrochemical Surface Oxidation Enhanced Raman Scattering (EC-SOERS) is a new phenomenon that provokes the enhancement of the Raman signal during the oxidation of a metal surface. Studies carried out so far indicate that carbonyl and carboxyl group are necessary to observe this phenomenon with a delocated charge being an important factor. In this work, the enhancement factors of EC-SOERS for different molecules, which present highly delocated charge and a carboxyl group, have been assessed. The systematic study of the enhancement factors helps to shed more light on the interaction of the molecules with the electrochemically generated SOERS substrates, yielding key information about the properties and specific features of this intriguing phenomenon. For the first time, a systematic information about the enhancement factors of this phenomenon is obtained. Analytical enhancement factors higher than 105 are obtained. Ministerio de Economía, y Competitividad (Grant CTQ2017-83935-R-AEI/FEDERUE), Junta de Castilla y León (Grant BU297P18) and Ministerio de Ciencia, Innovación y Universidades (Grant RED2018-102412-T). J.V.P-R. thanks Junta de Castilla y León for his postdoctoral fellowship (Grant BU033-U16). |
| Databáze: | OpenAIRE |
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