Origins of Polycyclic Aromatic Hydrocarbons in Sediments from the Danube and Sava Rivers and Their Tributaries in Serbia
Autor: | Jasmina B. Nikolić, Zoran Sekulić, Aleksandar D. Marinković, Dusan G. Antonovic, Dragan M. Crnković, Slađana Popović, Sasa Drmanic |
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Rok vydání: | 2020 |
Předmět: |
Hydrology
geography River sediment geography.geographical_feature_category 010504 meteorology & atmospheric sciences Danube River pollution sources 010501 environmental sciences 01 natural sciences 6. Clean water PAHs 13. Climate action Tributary Environmental Chemistry Environmental science river sediment Sava River 0105 earth and related environmental sciences General Environmental Science |
Zdroj: | Polish Journal of Environmental Studies |
ISSN: | 2083-5906 1230-1485 |
DOI: | 10.15244/pjoes/111319 |
Popis: | This study focussed on a comprehensive investigation on the state of pollution and identification of potential sources of contamination of some river sediments in Serbia by polycyclic aromatic hydrocarbons (PAHs), and is the basis for setting up further monitoring programs. The sediment quality of the Danube River (km 1433-845) and its tributaries in Serbia, including the Sava River (km 202-1), were analysed with respect to PAHs and total organic carbon (TOC). We found that total PAH concentration in the sediments from the Danube and its tributaries (10.0-4140 mu g kg(-1)) was lower than total PAH concentration in Sava River sediments (265.1-11272 mu g kg(-1)). Principal component analysis showed that concentrations of benzo[a]anthracene, chrysene, pyrene, fluoranthene, indeno[1,2,3- cd]pyrene, benzo[a] pyrene, benzo[b]fluoranthene and benzo[k]fluoranthene in the sediments were correlated with TOC. The diagnostic ratios anthracene/(anthracene+phenanthrene) and fluoranthene/(fluoranthene+ pyrene) were calculated to evaluate the emission sources of the PAHs. Therefore, these ratios indicated the predominantly pyrogenic source of the PAHs in the sediments. Results have also shown that river sediments in the Danube and Sava rivers and their tributaries were not recently polluted with PAHs, excluding only one location - S4, downstream of Sabac and characterized by heavily polluted sediment. |
Databáze: | OpenAIRE |
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