Complex of hexamethylenetetramine with magnesium-tetraphenylporphyrin: Synthesis, structure, spectroscopic characterizations and electrochemical properties
| Autor: | Habib Nasri, Frédérique Loiseau, Eric Saint-Aman, Arbia Ben Khelifa, Khaireddine Ezzayani |
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| Přispěvatelé: | Laboratoire de Chimie Hétérocyclique, Produits Naturels et Réactivité [Monastir] (CHPNR), Département de Chimie [Monastir], Faculté des Sciences de Monastir (FSM), Université de Monastir - University of Monastir (UM)-Université de Monastir - University of Monastir (UM)-Faculté des Sciences de Monastir (FSM), Université de Monastir - University of Monastir (UM)-Université de Monastir - University of Monastir (UM), Université de Monastir - University of Monastir (UM), Département de Chimie Moléculaire - Chimie Inorganique Redox Biomimétique (DCM - CIRE ), Département de Chimie Moléculaire (DCM), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019]) |
| Rok vydání: | 2017 |
| Předmět: |
Magnesium
Hydrogen bond Organic Chemistry Supramolecular chemistry chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Analytical Chemistry Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry X-ray crystallography [CHIM]Chemical Sciences Orthorhombic crystal system Hexamethylenetetramine Cyclic voltammetry 0210 nano-technology Single crystal ComputingMilieux_MISCELLANEOUS Spectroscopy |
| Zdroj: | Journal of Molecular Structure Journal of Molecular Structure, Elsevier, 2017, 1137, pp.412-418. ⟨10.1016/j.molstruc.2017.02.054⟩ |
| ISSN: | 0022-2860 |
| DOI: | 10.1016/j.molstruc.2017.02.054 |
| Popis: | A new crystalline material of a magnesium (II)–porphyrin complex was prepared and characterized by single crystal X-ray diffraction. The molecular structure is made by (5,10,15,20-tetraphenylporphyrinato-κ4N)bis(hexamethylenetetramine) magnesium dichloromethane disolvate. The title compound crystallizes in the orthorhombic system, space group Pbcn, with a = 19.2932 (6) A, b = 10.4878 (4) A, c = 26.0025 (14) A, V = 5261.4 (4) A3 and Z = 4. The supramolecular architecture includes weak C__H⋯N hydrogen bond. This magnesium-porphyrin species was also characterized by UV–visible, IR and fluorescence spectroscopy and a cyclic voltammetry investigation was also carried out on this species. |
| Databáze: | OpenAIRE |
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