Experimental and modeling study of benzaldehyde oxidation
| Autor: | Matteo Pelucchi, Frédérique Battin-Leclerc, Alessandro Stagni, Sylvain Namysl, Olivier Herbinet, Tiziano Faravelli, L. Pratali Maffei |
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| Přispěvatelé: | Laboratoire Réactions et Génie des Procédés (LRGP), Centre National de la Recherche Scientifique (CNRS)-Université de Lorraine (UL), Politecnico di Milano [Milan] (POLIMI) |
| Rok vydání: | 2020 |
| Předmět: |
Jet-stirred reactor
General Chemical Engineering Radical Kinetic analysis General Physics and Astronomy Energy Engineering and Power Technology 02 engineering and technology Photochemistry 01 natural sciences 7. Clean energy Aldehyde Benzaldehyde chemistry.chemical_compound 020401 chemical engineering Oxidation 0103 physical sciences Phenol [SPI.GPROC]Engineering Sciences [physics]/Chemical and Process Engineering 0204 chemical engineering chemistry.chemical_classification 010304 chemical physics Phenyl radical General Chemistry Toluene [CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry Fuel Technology chemistry 13. Climate action Gas chromatography Pyrolysis |
| Zdroj: | Combustion and Flame Combustion and Flame, Elsevier, 2020, 211, pp.124-132. ⟨10.1016/j.combustflame.2019.09.024⟩ |
| ISSN: | 0010-2180 |
| DOI: | 10.1016/j.combustflame.2019.09.024 |
| Popis: | International audience; Benzaldehyde is an aromatic aldehyde commonly considered in bio-oil surrogate formulation, and an important intermediate in the oxidation of other aromatic reference fuels such as toluene. However, its oxidation has never been previously investigated experimentally and no product formation profiles were reported in the very limited pyrolysis studies available in the literature. In this study, the gas-phase oxidation of benzaldehyde was investigated in a jet-stirred reactor. 48 species were detected using gas chromatography, mainly CO, CO2 and phenol. The important formation of CO and phenol indicates a rapid formation of phenyl radicals. This was confirmed by a kinetic analysis performed using the current version of the CRECK kinetic model, in which the reactions of phenyl radicals and oxygenated aromatic compounds have been updated. |
| Databáze: | OpenAIRE |
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