Rapid and Selective Catalytic Oxidation of Secondary Alcohols at Room Temperature by Using (N-Heterocyclic Carbene)-Ni0 Systems

Autor:	Jennifer Otten, Christophe Berini, Oscar Navarro, David A. Vicic, Ole H. Winkelmann
Rok vydání:	2010
Předmět:	Organic Chemistry chemistry.chemical_element General Chemistry Photochemistry Redox Catalysis Solvent Nickel chemistry.chemical_compound chemistry Catalytic oxidation Alcohol oxidation Selective catalytic oxidation Organic chemistry Carbene
Zdroj:	Chemistry - A European Journal. 16:6857-6860
ISSN:	0947-6539
Popis:	The selective, anaerobic catalytic oxidation of secondary alcohols at room temperature by using an in situ (N-heterocyclic carbene)-Ni(0) system is presented. The use of non-anhydrous, non-degassed 2,4-dichlorotoluene as both the oxidant and the solvent allows for very short reaction times and very high yields. In addition, a well-defined (N-heterocyclic carbene)-Ni(0) complex was synthesized and applied to these oxidation reactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b3afe8afc5e6146803d4903122393cf7 https://doi.org/10.1002/chem.201000220 Zobrazit plný text záznamu Plný text