Effect of Methoxy Substituents on Wet Peroxide Oxidation of Lignin and Lignin Model Compounds: Understanding the Pathway to C4 Dicarboxylic Acids
| Autor: | M. Filomena Barreiro, Alírio E. Rodrigues, Carlos A. Vega-Aguilar |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Depolymerization
General Chemical Engineering 02 engineering and technology General Chemistry 021001 nanoscience & nanotechnology Peroxide Industrial and Manufacturing Engineering chemistry.chemical_compound 020401 chemical engineering chemistry Succinic acid Lignin Organic chemistry 0204 chemical engineering 0210 nano-technology |
| Zdroj: | Repositório Científico de Acesso Aberto de Portugal Repositório Científico de Acesso Aberto de Portugal (RCAAP) instacron:RCAAP |
| ISSN: | 1520-5045 0888-5885 |
| DOI: | 10.1021/acs.iecr.0c05085 |
| Popis: | Lignin depolymerization through peroxide oxidation produces dicarboxylic acids (DCA), especially C4-DCA, like succinic acid. In this work, the effect of methoxy substituents on C4-DCA production using peroxide oxidation of lignin model compounds (p-hydroxybenzoic acid, vanillic acid, and syringic acid) and hardwood and softwood lignin samples was studied. It was concluded that methoxy substituents increased the reactivity toward peroxide oxidation. The succinic acid yield was higher for the model compounds with fewer methoxy groups, achieving 5.8 wt % of succinic acid for p-hydroxybenzoic acid. For Eucalyptus globulus kraft lignin (hardwood lignin with guaiacyl and syringyl units), an increased reactivity was verified, and more succinic acid (3.5 wt %) was produced in a shorter time, comparatively with Indulin AT lignin (softwood lignin, with only guaiacyl units), which produced 2.7 wt %. This evidence suggests that E. globulus kraft lignin might be a better raw material than Indulin AT for succinic acid production by peroxide oxidation. This work was financially supported by Base Funding − UIDB/50020/2020 of the Associate Laboratory LSRE-LCM − funded by national funds through FCT/MCTES (PIDDAC); Base Funding−UIDB/00690/2020 of CIMO, Centro de Investigação de Montanha−funded by national funds through FCT/MCTES (PIDDAC); COST Action LignoCOST (CA17128). C.A.V.-A. thanks the Costa Rican Science, Technology and Telecommunications Ministry for the Ph.D. Scholarship MICITT-PINN-CON-2-1-4-17-1-002. info:eu-repo/semantics/publishedVersion |
| Databáze: | OpenAIRE |
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