A General and Selective Synthesis of Methylmonochlorosilanes from Di-, Tri-, and Tetrachlorosilanes

Autor:	Yumiko Nakajima, Kei Sakamoto, Yuki Naganawa
Rok vydání:	2020
Předmět:	inorganic chemicals Catalytic transformation chemistry.chemical_compound chemistry Organic Chemistry Physical and Theoretical Chemistry Biochemistry Combinatorial chemistry Organosilicon
Zdroj:	Organic Letters. 23:601-606
ISSN:	1523-7052 1523-7060
DOI:	10.1021/acs.orglett.0c04175
Popis:	Direct catalytic transformation of chlorosilanes into organosilicon compounds remains challenging due to difficulty in cleaving the strong Si-Cl bond(s). We herein report the palladium-catalyzed cross-coupling reaction of chlorosilanes with organoaluminum reagents. A combination of [Pd(C
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::acb7758d3cc4225011fce72cc05b4a5e https://doi.org/10.1021/acs.orglett.0c04175 Zobrazit plný text záznamu