Synthesis and Characterization of Sodium Diphenylcarbamodithioate Ligand [L] and its Cobalt, Nickel, and Copper Complexes
| Autor: | Bashdar I. Meena, Aeed S. Al-Fahdawi, Eman I. Alsalihi |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Technology
Science Metal ions in aqueous solution Sodium Inorganic chemistry chemistry.chemical_element Infrared spectroscopy 010402 general chemistry 01 natural sciences Metal General Environmental Science 010405 organic chemistry Chemistry Ligand Agriculture structural study Magnetic susceptibility Copper 0104 chemical sciences diphenylcarbamodithioate complexes four-coordinate square planar complexes visual_art visual_art.visual_art_medium General Earth and Planetary Sciences sodium diphenylcarbamodithioate ligand Powder diffraction Nuclear chemistry |
| Zdroj: | ARO-The Scientific Journal of Koya University, Vol 5, Iss 2, Pp 1-5 (2017) |
| ISSN: | 2307-549X 2410-9355 |
| Popis: | A correlation of the infrared spectra of thiocarbonyl derivatives based on the literature data has been carried out. Assignments have also been made in some new systems. Sodium Diphenylcarbamodithioate ligand and its monomeric complexes were synthesized at room temperature and stirring condition. The ligand and its complexes of the general formula [M(L) 2 ] (where M= Co +2 , Ni +2 and Cu +2 ) were characterized by spectroscopic methods (IR and ultraviolet-visible), elemental analysis (C.H.N. and S) metal content, magnetic susceptibility measurement, and biological activity (an antibacterial activity of the complex was studied by agar disc diffusion method and minimum inhibitory concentration strain against Staphylococcus aureus and Bacillus subtilis). The complex exhibited significant activities against S. aureus and B. subtilis, thin-layer chromatography, mass spectrometry, X-ray powder diffraction, and molar conductance. Our study revealed the formation of four-coordinate square planar complexes around Coп, Niп, and Cuп metal ions. |
| Databáze: | OpenAIRE |
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