A new homobimetallic cobalt(II) complex based on the tetradentate 3,5-bis(2-pyridyl)-1H-1,2,4-triazole ligand: Synthesis, crystal structure, Hirshfeld analysis, spectroscopic characterization, magnetic properties and antimicrobial activities
| Autor: | Mohamed Saadi, Fouad Bentiss, Olivier Mentré, Lahcen El Ammari, El Mostafa Ketatni, Siham Esserti, Mohammed Faize, Abdelhakim Laachir, Salaheddine Guesmi |
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| Přispěvatelé: | Unité de Catalyse et Chimie du Solide - UMR 8181 (UCCS), Université d'Artois (UA)-Centrale Lille-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS), Centrale Lille Institut (CLIL)-Université d'Artois (UA)-Centrale Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Lille |
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
4-triazolate
Stacking chemistry.chemical_element Magnetic property Crystal structure Triclinic crystal system Antimicrobial activity 010402 general chemistry 01 natural sciences Inorganic Chemistry chemistry.chemical_compound Materials Chemistry Hirshfeld surface analysis [CHIM]Chemical Sciences Physical and Theoretical Chemistry 5-Bis(2-pyridyl)-1 Homobimetallic Co II complex 010405 organic chemistry Hydrogen bond [CHIM.ORGA]Chemical Sciences/Organic chemistry 1 2 4-Triazole 0104 chemical sciences Crystallography chemistry Octahedron Single crystal Cobalt |
| Zdroj: | Polyhedron Polyhedron, 2020, 189, pp.114722. ⟨10.1016/j.poly.2020.114722⟩ Polyhedron, Elsevier, 2020, 189, pp.114722. ⟨10.1016/j.poly.2020.114722⟩ |
| ISSN: | 0277-5387 |
| DOI: | 10.1016/j.poly.2020.114722⟩ |
| Popis: | A novel homobimetallic cobalt(II) complex, [Co2(bpt)2(H2O)4](NO3)2·2H2O (bpt = 3,5-bis(2-pyridyl)-1,2,4-triazolate), has been synthesized and characterized by single crystal X-ray diffraction, Hirshfeld surface analysis, as well as UV–Visible and FTIR techniques. The crystal structure determination shows that the dinuclear complex crystallizes in the triclinic crystal system with the P 1 - space group. The (N′,N1,N2,N″)2 double bridging coordination mode is realised with a distorted octahedral N4O2-coordinated cobalt centre. The structure cohesion is ensured by different intermolecular hydrogen bonds, π–π stacking interactions and intermolecular lone-pair···π interactions. The structure consists of [Co2(bpt)2]2+ dimeric units with a cobalt-cobalt distance of 4.170(2) A. Magnetic measurements carried out on the homobimetallic complex indicate a relatively weak antiferromagnetic interaction between the two cobalt centres. This complex exhibited antimicrobial activity against several strains of the fungal phytopathogens Verticillium dahliae and Fusarium oxysporum fsp. melonis, as well as against the phytopathogenic bacteria Agrobacterium tumefaciens, suggesting its use in crop protection. |
| Databáze: | OpenAIRE |
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