Synergistic π–π and Pt–Pt interactions in luminescent hybrid inorganic/organic dual columnar liquid crystals

Autor:	César L. Folcia, Rubén Chico, Jesús Etxebarria, Silverio Coco, Emiliano Tritto, Josu Ortega, Pablo Espinet
Rok vydání:	2015
Předmět:	Diffraction Materials science Mesogen Stacking Triphenylene Mesophase General Chemistry Liquid Crystals Chemistry chemistry.chemical_compound Crystallography chemistry Liquid crystal Materials Chemistry Phosphorescence Luminescence
Zdroj:	UVaDOC. Repositorio Documental de la Universidad de Valladolid instname
ISSN:	2050-7534 2050-7526
DOI:	10.1039/c5tc01802a
Popis:	Producción Científica A new triphenylene-isocyanide CN-C6H4-O-(CH2)6-TriPh, non mesogenic, and their ortho-metallated benzoquinolate (bzq) complexes, [M(bzq)X(CN-C6H4-O-(CH2)6-TriPh)] (M = Pd, Pt; X = Cl, I) and [Pt(bzq)(CN-C6H4-O-(CH2)6-TriPh)2]A (A = NO3−, BF4−, PF6−), all displaying a columnar mesophase, have been prepared. The structure of the mesophase, determined by X-ray diffraction methods, is uncommon and consists of a central column formed by stacking of the organometallic benzoquinoline-platinum fragments, surrounded by six columns in hexagonal disposition formed by stacking of the triphenylene groups. These materials show aggregation-induced phosphorescence based on inter-disk Pt⋯Pt interactions. 2017-02-15 Junta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA302U13) Ministerio de Economía, Industria y Competitividad (CTQ2014-52796-P) Ministerio de Economía, Industria y Competitividad (MAT2012-38538-C03-02) Gobierno Vasco (GI/IT-449-10)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a84ccb4f44fd3183d7dd0965f9c44ec5 https://doi.org/10.1039/c5tc01802a Zobrazit plný text záznamu