Synthesis of diethylcarbonate by ethanolysis of urea: A study on the recoverability and recyclability of new Zn-based heterogeneous catalysts

Autor:	Francesco Ruffo, Elvira De Giglio, Maria Elena Cucciolito, Daniel Curulla-Ferré, Antonella Angelini, Brunella Maria Aresta, Angela Dibenedetto, Stefania Fasciano, Michele Aresta
Přispěvatelé:	Di Benedetto, A., Angelini, A., Aresta, Michele, Fasciano, S., Cucciolito, MARIA ELENA, Ruffo, Francesco, Aresta, Brunella, Curulla Ferre, D., De Giglio, E.
Rok vydání:	2015
Předmět:	chemistry.chemical_compound chemistry Process Chemistry and Technology Inorganic chemistry Urea chemistry.chemical_element Zinc Leaching (metallurgy) Reuse Catalysis
Zdroj:	Applied Catalysis A: General. 493:1-7
ISSN:	0926-860X
Popis:	New Zn-based catalysts are described that act as heterogenized or heterogeneous catalysts, with easy recovery and re-utilization with a limited or even zero Zn-leaching. For stabilizing in the heterogeneous form the catalytically active Zn centre, mixed oxides, ZIF-8 and Zn-tethered systems have been synthesized and found to sensibly reduce the leaching of Zn in solution with respect to ZnO, making possible their recovery and reuse. ZIF-8 can be used for long time of reaction, reaching high DEC yields (comparable or higher than those obtained with ZnO) without any significant loss of zinc.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a5974b8f9dacb0eef356cc1a3409ac9e https://doi.org/10.1016/j.apcata.2014.12.050 Zobrazit plný text záznamu Full Text from ScienceDirect