New insights into the study of the destabilization of oil-in-water emulsions with dextran sulfate provided by the use of light scattering methods
Autor: | Véronique Bosc, Laure Degrand, Camille Michon |
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Přispěvatelé: | Ingénierie, Procédés, Aliments (GENIAL), Institut National de la Recherche Agronomique (INRA)-AgroParisTech, Conservatoire National des Arts et Métiers [CNAM] (CNAM) |
Jazyk: | angličtina |
Rok vydání: | 2016 |
Předmět: |
Diffusing-wave spectroscopy
Flocculation chemical physics Chromatography Chemistry General Chemical Engineering food [SDV]Life Sciences [q-bio] Kinetics 04 agricultural and veterinary sciences General Chemistry 040401 food science light scattering Light scattering Colloid 0404 agricultural biotechnology Chemical engineering mixed system colloids Emulsion Elasticity (economics) Spectroscopy dispersed system Food Science |
Zdroj: | Food Hydrocolloids Food Hydrocolloids, Elsevier, 2016, 52, pp.848-856. ⟨10.1016/j.foodhyd.2015.08.021⟩ |
ISSN: | 0268-005X 1873-7137 |
DOI: | 10.1016/j.foodhyd.2015.08.021⟩ |
Popis: | Emulsions are non-thermodynamically-stable systems. Being able to characterize their evolution upon time without disturbing them would be of great interest. Mechanisms of destabilization: depletion and bridging flocculation were reproduced by using dextran sulfate respectively with Tween 20 and whey-protein-stabilized oil-in-water emulsions. Two light scattering methods were combined: Multiple Light Scattering, MLS, specially adapted to characterize turbid systems (Turbiscan®) and Multi-Speckle Diffusing Wave Spectroscopy, MS-DWS (Rheolaser™). The Tween 20-stabilized emulsion showed a very stable-versus-time elasticity index (EI) measured by MS-DWS up to 24 h. On the contrary, the whey-protein-stabilized emulsions showed a large variation of EI that decreased continuously during 10 h and dropped to zero suddenly. On the basis of the physico–chemical interaction knowledge and the MLS profile evolution versus time, a variation of the destabilization kinetics depending on the droplet network stabilization but also on the interactions between droplets and the surface of the recipient was proposed. It was confirmed by the modification of the destabilization kinetics when changing the solid surface tension of the recipient. |
Databáze: | OpenAIRE |
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