Gas-phase ionic reactions: dynamics and mechanism of nucleophilic displacements

Autor:	Colleen K. Regan, Stephen L. Craig, Michael L. Chabinyc, John I. Brauman
Rok vydání:	1998
Předmět:	Reaction rate Multidisciplinary Nucleophile Chemistry Reaction dynamics Elementary reaction Solvation SN2 reaction Thermodynamics Physical chemistry Reactivity (chemistry) Chemical reaction
Zdroj:	Science (New York, N.Y.). 279(5358)
ISSN:	1095-9203
Popis:	Nucleophilic displacement reactions (the S N 2 reaction) of ions in the gas phase are a prototypical reaction system that allows a study of dynamics, mechanisms, and structure-energy relations. This article reviews aspects of the kinetics (especially the applicability of statistical reaction rate theory), the relation of structure and reactivity, and the effects of small numbers of solvent molecules on the reaction and compares the behavior of the ionic reaction in the gas phase with that in solution.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a00770c9ff835e23277729b6591823a8 https://pubmed.ncbi.nlm.nih.gov/9506930 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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