A Hydronium Solvate Ionic Liquid: Ligand Exchange Conduction Driven by Labile Solvation
| Autor: | Takashi Nagata, Shun Takeoka, Atsushi Kitada, Kuniaki Murase, Masayuki Saimura, Masato Katahira, Kazuhiro Fukami, Kohei Kintsu |
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| Rok vydání: | 2018 |
| Předmět: |
Hopping Conduction
Hydronium Renewable Energy Sustainability and the Environment Ligand Solvation 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics Thermal conduction Photochemistry 01 natural sciences Labile Solvation 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Ionic liquid Materials Chemistry Electrochemistry Hydronium Solvate Ionic Liquid 0210 nano-technology |
| Zdroj: | Journal of The Electrochemical Society. 165:H496-H499 |
| ISSN: | 1945-7111 0013-4651 |
| DOI: | 10.1149/2.0971809jes |
| Popis: | We observed a new class of proton conduction in a hydronium (H₃O⁺) solvate ionic liquid (IL). The IL is described as [H₃O⁺·18C6]Tf₂N⁻; Tf = CF₃SO₂) anion. Self-diffusion coefficient measurements revealed that protons of H₃O⁺ (solute ion) move faster than 18C6 ligand (solvent), marking the first observation of ligand exchange conduction not only among solvate ILs but also among protic ILs without free neutral molecules. The presence of ligand exchange conduction without inducing external electric field indicates that solvation of H₃O⁺ by 18C6 is kinetically labile, i.e. ligand exchange is very fast for the reaction H₂O + 18C6 + HTf₂N ⇌ H₃O⁺·18C6]Tf₂N, while the equilibrium shifts to the right. The fundamental findings regarding the hydronium solvate IL will help in the design of proton conductors. |
| Databáze: | OpenAIRE |
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