Intramolecular Nitrene Transfer via the C≡N Bond Cleavage of Acetonitrile to a μ3-Alkylidyne Ligand on a Cationic Triruthenium Plane
| Autor: | Toshiro Takao, Atsushi Tahara, Yusuke Takahashi |
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| Rok vydání: | 2020 |
| Předmět: | |
| Zdroj: | Organometallics. 39:2888-2899 |
| ISSN: | 1520-6041 0276-7333 |
| DOI: | 10.1021/acs.organomet.0c00393 |
| Popis: | The μ3-η2-iminoacyl-μ3-hexylidyne complex, [(Cp*Ru)3(μ3-CC5H11)(μ3-η2-HN═CMe)(μ-H)] (2a) (Cp* = η5-C5Me5), was prepared by the reaction of the μ3-η2:η2(⊥)-hexyne complex, [{Cp*Ru(μ-H)}3(μ3-η2:η2-nB... |
| Databáze: | OpenAIRE |
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