| Autor: |
Lu Lin, Zening Liu, Uvinduni I. Premadasa, Tianyu Li, Ying-Zhong Ma, Robert L. Sacci, John Katsaras, Kunlun Hong, C. Patrick Collier, Jan-Michael Y. Carrillo, Benjamin Doughty |
| Rok vydání: |
2022 |
| Předmět: |
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| Zdroj: |
The Journal of Physical Chemistry Letters. 13:10889-10896 |
| ISSN: |
1948-7185 |
| DOI: |
10.1021/acs.jpclett.2c02921 |
| Popis: |
Conventional wisdom suggests that cations play a minimal role in the assembly of cationic amphiphiles. Here, we show that at liquid/liquid (L/L) interfaces, specific cation effects can modulate the assemblies of hydrophobic tails in an oil phase despite being attached to cationic headgroups in the aqueous phase. We used oligo-dimethylsiloxane (ODMS) methyl imidazolium amphiphiles to identify these specific interactions at hexadecane/aqueous interfaces. Small cations, such as Li |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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