Benefits of ozonation before activated carbon adsorption for the removal of organic micropollutants from wastewater effluents

Autor: Romain Mailler, Catherine Morlay, Ronan Guillossou, Julien Le Roux, Vincent Rocher, Stephan Brosillon, Emmanuelle Vulliet, Fabrice Nauleau, Johnny Gasperi
Přispěvatelé: laboratoire Eau, Environnement et Systèmes Urbains (LEESU), AgroParisTech-Université Paris-Est Marne-la-Vallée (UPEM)-École des Ponts ParisTech (ENPC)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12), Laboratoire Eau Environnement et Systèmes Urbains (LEESU), AgroParisTech-École des Ponts ParisTech (ENPC)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12), Institut Européen des membranes (IEM), Université de Montpellier (UM)-Université Montpellier 2 - Sciences et Techniques (UM2)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS), SIAAP - Direction du Développement et de la Prospective, SIAAP, Institut des Sciences Analytiques (ISA), Centre National de la Recherche Scientifique (CNRS)-Université de Lyon-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-École normale supérieure - Lyon (ENS Lyon), Matériaux, ingénierie et science [Villeurbanne] (MATEIS), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Centre National de la Recherche Scientifique (CNRS)-Institut National des Sciences Appliquées de Lyon (INSA Lyon), Université de Lyon-Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA), SAUR - Direction de la Recherche et Développement, SAUR, École des Ponts ParisTech (ENPC)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12), Centre National de la Recherche Scientifique (CNRS)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM), SIAAP - Direction Innovation, TRACES - Technologie et Recherche en Analyse Chimique pour l'Environnement et la Santé, Institut de Chimie du CNRS (INC)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Centre National de la Recherche Scientifique (CNRS), Université de Lyon-Université de Lyon-Institut National des Sciences Appliquées de Lyon (INSA Lyon), Université de Lyon-Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS), Eau et Environnement (GERS-LEE ), Université Gustave Eiffel, OPUR, Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
Jazyk: angličtina
Rok vydání: 2019
Předmět:
EAU USEE
Powdered activated carbon treatment
Environmental Engineering
Ozone
WASTEWATER ADVANCED TREATMENT
Health
Toxicology and Mutagenesis
0208 environmental biotechnology
ACTIVATED CARBON ADSORPTION
02 engineering and technology
TRAITEMENT DE L&apos
010501 environmental sciences
Wastewater
MICROPOLLUANT
01 natural sciences
Waste Disposal
Fluid
complex mixtures
Water Purification
chemistry.chemical_compound
Adsorption
Dissolved organic carbon
medicine
Environmental Chemistry
Nitrite
0105 earth and related environmental sciences
ORGANIC MICROPOLLUTANTS
Bromates
[SDE.IE]Environmental Sciences/Environmental Engineering
Public Health
Environmental and Occupational Health
General Medicine
General Chemistry
Bromate
Pollution
6. Clean water
020801 environmental engineering
chemistry
EAU
Environmental chemistry
Charcoal
[SDE]Environmental Sciences
[CHIM.OTHE]Chemical Sciences/Other
Water Pollutants
Chemical
Activated carbon
medicine.drug
OZONATION
Zdroj: Chemosphere
Chemosphere, Elsevier, 2019, 34 p
Chemosphere, Elsevier, 2020, 245, pp.125530. ⟨10.1016/j.chemosphere.2019.125530⟩
ISSN: 0045-6535
DOI: 10.1016/j.chemosphere.2019.125530⟩
Popis: International audience; Advanced processes for the removal of organic micropollutants (OMPs) from wastewater effluents include adsorption onto activated carbon, ozonation, or a combination of both processes. The removal of 28 OMPs present in a real wastewater effluent was studied by ozonation coupled to activated carbon adsorption and compared to a sole adsorption. The influence of the specific ozone dose (0.09–1.29 gO3/gDOC) and the influence of the powdered activated carbon (PAC) dose (2, 5 and 10 mg/L) were first studied separately. OMPs removal increased with both the specific ozone dose (up to 80% for a dose higher than 0.60 gO3/gDOC) and the PAC dose. Ozonation performances decreased in presence of suspended solids, which were converted to dissolved organic carbon. A correction of the specific ozone dose according to the suspended solids levels, in addition to nitrite, should be considered. The influence of ozonation (0.09, 0.22, 0.94 and 1.29 gO3/gDOC) on OMPs adsorption was then assessed. OMPs adsorption didn’t change at low specific ozone doses but increased at higher specific ozone doses due to a decrease in DOM adsorption and competition with OMPs. At low ozone doses followed by adsorption (0.22 gO3/gDOC and 10 mg/L PAC), the two processes appeared complementary as OMPs with a low reactivity toward ozone were well absorbed onto PAC while most OMPs refractory to adsorption were well eliminated by ozone. Improved removals were obtained for all compounds with these selected doses, reaching more than 80% removal for most OMPs while limiting the formation of bromate ion.
Databáze: OpenAIRE
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