| Popis: |
High-density polyethylene (HDPE) pipe is one of the materials of interest for use in road drainage systems. The combination of ultraviolet (UV) light, temperature, and moisture can produce weak spots and lead to pipe degradation during the storage, installation, and repair process. The objective of this study was to evaluate changes in the chemical, morphological structure, and thermomechanical properties of recycled and virgin pipes under UV exposure. Laboratory accelerated aging tests were conducted by exposing pipes to UV for 3600 hours with an irradiance of 0.89 W/(m2 nm) at a wavelength of 340 nm. A cycle of 12 hours—comprised of 8 hours of UV radiation at 60°C and 4 hours of no UV radiation at 50°C corresponding to no water condensation—was performed to condition the specimens. HDPE specimens were taken out after 3600 hours and analyzed with FTIR (Fourier-transform infrared spectroscopy), SEM (scanning electron microscopy), DSC (differential scanning calorimetry), oxidative-induction time (OIT) measurements, and tensile tests. The results show that the recycled pipes maintained good properties and were not significantly affected by UV radiation, similarly to the virgin pipes. Statistical analysis using one-way analysis of variance (ANOVA) shows that there was no significant difference between tensile strength, elastic modulus, and hardness measurements before and after UV exposure. There were only a few small changes in the surface of the pipes. The addition of carbon black, antioxidants, and UV stabilizers prevented further aging of the pipes during UV exposure. |
