Magnesiation of isodicyclopentadiene. Formation of sandwich and monomeric complexes and the stereoselectivity of their reactions with transition metal halides

Autor:	Jeffrey D. Schloss, Bernard Gautheron, Sébastien Gentil, Philippe Meunier, Olivier Gobley, Robin D. Rogers, Judith C. Gallucci, Leo A. Paquette
Předmět:	Magnesium Organic Chemistry Halide chemistry.chemical_element Alkali metal Photochemistry Inorganic Chemistry chemistry.chemical_compound Monomer 13c nmr spectroscopy Transition metal chemistry Polymer chemistry Stereoselectivity Physical and Theoretical Chemistry TMEDA complex
Zdroj:	Scopus-Elsevier
Popis:	The exo,exo-bis(isodicyclopentadienyl)magnesium sandwich and the monomeric exo-(isodicyclopentadienyl)butylmagnesium TMEDA complex have been synthesized and characterized by 1H and 13C NMR spectroscopy in C6D6 solution. The solid-state structures were determined by X-ray crystallography. The stereoselectivity with which both moisture-sensitive compounds react with TiCl3·3THF and ZrCl4 was assessed and suitably compared to related observations recorded for alkali metal (Li+, Na+, and K+) complexes of isodicyclopentadiene.
Databáze:	OpenAIRE
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