Synthesis and Shaping Scale-up Study of Functionalized UiO-66 MOF for Ammonia Air Purification Filters
| Autor: | David Farrusseng, Yoldes Khabzina, Hans-Juergen Richter, Helge Reinsch, Jérémy Dhainaut, Norbert Stock, Matthias Ahlhelm |
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| Přispěvatelé: | IRCELYON-Ingéniérie, du matériau au réacteur (ING), Institut de recherches sur la catalyse et l'environnement de Lyon (IRCELYON), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut fur Anorganische Chemie, Christian-Albrechts-Universität zu Kiel (CAU), Publica |
| Rok vydání: | 2018 |
| Předmět: |
Materials science
General Chemical Engineering Batch reactor chemistry.chemical_element 02 engineering and technology 010402 general chemistry 01 natural sciences Industrial and Manufacturing Engineering Ammonia chemistry.chemical_compound breakthrough measurements Ammonia adsorption Air purification Zirconium [SDE.IE]Environmental Sciences/Environmental Engineering [CHIM.MATE]Chemical Sciences/Material chemistry General Chemistry 021001 nanoscience & nanotechnology Aqueous suspension 6. Clean water 0104 chemical sciences chemistry Chemical engineering SCALE-UP UiO66-COOH 0210 nano-technology |
| Zdroj: | Industrial and engineering chemistry research Industrial and engineering chemistry research, American Chemical Society, 2018, 57 (24), pp.8200-8208. ⟨10.1021/acs.iecr.8b00808⟩ Industrial & Engineering Chemistry Research |
| ISSN: | 1520-5045 0888-5885 |
| DOI: | 10.1021/acs.iecr.8b00808 |
| Popis: | SSCI-VIDE+ING+YKH:DFA; International audience; We report herein the upscaled synthesis and shaping of UiO66-COOH for NH3 air purification. The synthesis of the zirconium-based MOF was carried out in a batch reactor in an aqueous suspension with a yield of 89% and a space-time yield of 350 kg/day/m3. Neither toxic chemicals nor organic solvents were used, allowing this MOF to be employed in individual or collective air purification devices. Freeze-granulation and extrusion shaping techniques were investigated. The NH3 air purification performances of UiO66-COOH in bead, tablet and extrudate forms were compared to those of commercial carbon based materials (type K adsorbents from3M and Norit). Testing conditions were chosen to reflect current standards for ammonia concentration (600–1200 ppm) and velocity. In addition, the breakthrough measurements were carried out at three different relative humidity levels (0%, 40%, and 70%). Pellets and extrudates of UiO66-COOH outperformed commercial benchmark adsorbents in all conditions, especially in dry conditions, for which the commercial adsorbents suffered impaired ammonia uptake and shortened service life. Extrudates of UiO66-COOH also withstood attrition after intensive shaking. |
| Databáze: | OpenAIRE |
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