Structural isolation of NIR absorbing ferrocenyl bridged N-confused fused expanded phlorin, N-confused porphodimethene and the π-extended corrorin isomer: synthesis and characterization

Autor:	Dandamudi Usharani, Harapriya Rath, Raja Narayansamy, Sumit Sahoo, Buddhadeb Chakraborty
Rok vydání:	2021
Předmět:	Inorganic Chemistry Crystallography Chemistry Absorption band Solid-state Moiety Crystal structure Absorption (chemistry) Characterization (materials science)
Zdroj:	Dalton Transactions. 50:14421-14431
ISSN:	1477-9234 1477-9226
DOI:	10.1039/d1dt02385c
Popis:	Concise syntheses and spectroscopic, solid state X-ray crystal structure and theoretical studies of three electronically appealing new generation hitherto unknown ferrocenyl bridged N-confused heterocyclic macrocycles with (without) fusion are reported. Intriguingly, the expanded N-confused fused phlorin (1.1.1.1.1) with the built-in tripentacyclic [5.5.5] moiety exhibits tailing of the NIR absorption band beyond 1000 nm while the nonconjugated porphodimethene and a new generation π-extended isomeric corrorin analogue exhibit UV-vis absorption.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::92574b9214027eac682116637c573c23 https://doi.org/10.1039/d1dt02385c Zobrazit plný text záznamu