Ultrafast kinetics of linkage isomerism in Na2[Fe(CN)5NO] aqueous solution revealed by time-resolved photoelectron spectroscopy
| Autor: | Igor Yu. Kiyan, Azhr A. Raheem, Oliver Kühn, Mario Borgwardt, Sergey I. Bokarev, Christoph Merschjann, Nicholas Engel, Martin Wilke, Gilbert Grell, Emad F. Aziz, Saadullah G. Aziz |
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| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
Radiation
Aqueous solution Chemistry Kinetics 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics Photochemistry 01 natural sciences 0104 chemical sciences Photoexcitation X-ray photoelectron spectroscopy Metastability Excited state lcsh:QD901-999 lcsh:Crystallography Linkage isomerism 0210 nano-technology Instrumentation Isomerization Spectroscopy |
| Zdroj: | Structural Dynamics, Vol 4, Iss 4, Pp 044031-044031-15 (2017) |
| ISSN: | 2329-7778 |
| Popis: | The kinetics of ultrafast photoinduced structural changes in linkage isomers is investigated using Na2[Fe(CN)5NO] as a model complex. The buildup of the metastable side-on configuration of the NO ligand, as well as the electronic energy levels of ground, excited, and metastable states, has been revealed by means of time-resolved extreme UV (XUV) photoelectron spectroscopy in aqueous solution, aided by theoretical calculations. Evidence of a short-lived intermediate state in the isomerization process and its nature are discussed, finding that the complete isomerization process occurs in less than 240 fs after photoexcitation. |
| Databáze: | OpenAIRE |
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