(Bio)molecular surface patterning by phototriggered oxime ligation
| Autor: | Hans G. Börner, Martin Bastmeyer, Guillaume Delaittre, Michael Bruns, Thomas Pauloehrl, Christopher Barner-Kowollik, Maria Meißler |
|---|---|
| Rok vydání: | 2012 |
| Předmět: |
chemistry.chemical_classification
Surface Properties Ultraviolet Rays Spectrometry Mass Secondary Ion Peptide General Chemistry Mass spectrometry Oxime Combinatorial chemistry Aldehyde Catalysis chemistry.chemical_compound chemistry Polymer chemistry Oximes Click chemistry Click Chemistry Molecular surfaces Amino Acid Sequence Ligation Peptides Ultraviolet radiation |
| Zdroj: | Angewandte Chemie (International ed. in English). 51(36) |
| ISSN: | 1521-3773 |
| Popis: | Making light work of ligation: A novel method utilizes light for oxime ligation chemistry. A quantitative, low-energy photodeprotection generates aldehyde, which subsequently reacts with aminooxy moieties. The spatial control allows patterning on surfaces with a fluoro marker and GRGSGR peptide, and can be imaged by time-of-flight secondary-ion mass spectrometry. |
| Databáze: | OpenAIRE |
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