Angle distortion model for predicting enediyne activation towards Bergman cyclization: an alternate to the distance theory

Autor:	Prabuddha Bhattacharya, Soham Chakraborty, Ashwin Balaji, Amit Basak
Rok vydání:	2022
Předmět:	General Chemical Engineering General Chemistry
Zdroj:	RSC advances. 12(36)
ISSN:	2046-2069
Popis:	Structurally similar enediynes showed decrease in interior proximal bond angles (Pa and Pb) with increase in reactivity. Enediynes with average interior proximal angles [(Pa + Pb)/2] less than 166° undergo cyclization under ambient conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::85f45f957a4f6baefcbb6c2f581c0972 https://pubmed.ncbi.nlm.nih.gov/36090394 Zobrazit plný text záznamu