Generation of a zinc and rhodium containing metallomacrocycle by rearrangement of a six-coordinate precursor complex

Autor:	Sabine Becker, Yu Sun, Cedric Groß, T Jost, Gereon Niedner-Schatteburg, Werner R. Thiel, Matthias P. Klein, Tobias Grimm
Rok vydání:	2020
Předmět:	Metals and Alloys chemistry.chemical_element General Chemistry Zinc Medicinal chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Rhodium chemistry.chemical_compound chemistry Materials Chemistry Ceramics and Composites Chelation Phosphine
Zdroj:	Chemical Communications. 56:368-371
ISSN:	1364-548X 1359-7345
DOI:	10.1039/c9cc07723e
Popis:	Two pentadentate N3,P2 ligands coordinate zinc(ii) by their N3 pocket. Four free phosphine donors allow the coordination of four AuCl moieties leading to a pentanuclear ZnAu4 complex. In contrast, the attempt to use the phosphines for chelating coordination of two Rh(CO)Cl units results in a well-organized rearrangement that ends up with the formation of a metallomacrocycle in high yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::829646de253a97a2f7a06f521a5ba5af https://doi.org/10.1039/c9cc07723e Zobrazit plný text záznamu